H₂O₂/UV-C treatment of textile preparation wastewater: kinetic investigation on alternative combinations of commercial textile preparation auxiliaries

Abstract

Four different textile preparation effluents were simulated to examine the applicability of the hydrogen peroxide/ultraviolet-C (H₂O₂/UV-C ) advanced oxidation process for the treatment of real textile preparation (desizing, scouring and bleaching) wastewater bearing the non-ionic surfactant nonyl phenol decaethoxylate (NP-10). In the absence of any textile preparation chemical, NP-10 degradation was complete in 15 min (rate coefficient: 0.22 min⁻¹) accompanied by 78% chemical oxygen demand (COD) (rate coefficient: 0.026 min⁻¹) and 57% total organic carbon (TOC) (rate coefficient: 0.014 min⁻¹) removals achieved after 60 min photochemical treatment. H₂O₂ consumption rates were not significantly affected by the introduction of carbonate and chloride ions (average rate coefficient: 0.032 min⁻¹) at pH values<11.5, above which H₂O₂ dissociation to its conjugate base became pronounced. The organic, phosphonate-based sequestering agents competed with NP-10 for UV-C light absorption and HO^• radicals. H₂O₂/UV-C oxidation of the simulated textile preparation effluent containing 3.0 g L⁻¹ Cl⁻, 1.5 g L⁻¹ NaOH and 1.0 g L⁻¹ diethylenetriamine pentamethylene phosphonic acid (DTPMP) resulted in the worst treatment performance due to its high pH and organic carbon content. For this textile preparation effluent, NP-10 abatement was complete in 100 min (rate coefficient: 0.018 min⁻¹), while COD and TOC removals dropped down to only 16% and 8%, respectively, achieved after 60 min treatment. The highest H₂O₂/UV-C oxidation efficiency resulting in 34% COD and 28% TOC removals was obtained for the simulated textile preparation effluent comprising of 3.0 g L⁻¹ Cl⁻, 1.5 g L⁻¹ NaOH and 1.0 g L⁻¹ 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP). For this textile preparation effluent, NP-10 degradation was complete after 50 min (rate coefficient: 0.061 min⁻¹) exposure to H₂O₂/UV-C treatment.

Keywords:

• H₂O₂/UV-C
• oxidation
• hydroxyl radical scavengers
• nonyl phenol decaethoxylate (NP-10)
• phosphonic acid-based sequestering agents
• textile preparation effluent

Acknowledgements

The authors acknowledge the financial support of the Scientific and Technological Research Council of Turkey (TUBITAK) under project number 108Y051.