Adsorption of azo dyes using peanut hull and orange peel: a comparative study

Abstract

This work proposes the use of agro-industrial wastes, specifically peanut hull (HP) and orange peel (OP), as adsorbents for dyes, such as Remazol Golden Yellow RNL-150% (RYG), Gray Reactive BF-2R (RG) and Reactive Turquoise Q-G125 (RT). Characterization by Brunauer-Emmett-Teller indicates that the adsorbents are mesoporous, with pH_zpc values of 5.0 for HP and 4.0 for OP. Fourier transform-infrared spectroscopy identified carbonyl and sulphonic groups. The initial pH of the best-adsorbing solution of the three colours was 2.0. Increasing the concentration of the adsorbent promoted an increase in the percentage of removal until saturation of the adsorbent. In a factorial design, the largest value of q was obtained with 0.25 g of the adsorbent, with a particle size of<0.4 mm and a stirring speed of 300 rpm. Such conditions were used in kinetic studies and studies of adsorption equilibrium. The evolution kinetics were rapid in the first few minutes, and after 180 min the system reached equilibrium. The kinetic model that best fit the experimental data to a 95% confidence level for the F test was the pseudo-second-order model for RYG/HP, RG/OP and RT/OP. There was no significant difference between the kinetic models as evaluated by the F test for RYG/OP, RG/HP and RT/HP. The experimental results indicated favourable dye adsorption characteristics for the adsorbents studied. The results of the F test showed that for RYG and RG, there was no significant difference between the two evaluated models. This study suggests that HP and OP are viable alternatives for the treatment of effluents containing RYG, RG and RT dyes.

Keywords:

• adsorption
• dye
• wastewater
• agroindustrial residue

Acknowledgements

The authors thank Texpal for providing the dyes, Amendolândia and Habib's for the peanut hull and orange peel, respectively.

The authors thank the Centro de Tecnologias Estratégicas do Nordeste (CETENE) for providing help with the characterization of adsorbents.

Funding

The authors acknowledge Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) for financial support. The authors thank the scholarship programme PIBIC/UFPE and PIBIC/FACEPE provided funding through IC grants,