Desalination of saline water via forward osmosis using magnetic nanoparticles covalently functionalized with citrate ions as osmotic agent

ABSTRACT

Forward osmosis is an emerging membrane technology in water desalination. In this study, desalination of saline water via forward osmosis was investigated using a new magnetic osmotic agent. For this purpose, Fe₃O₄ nanoparticles covalently functionalised with tri-sodium citrate was synthesised and characterised. The structural examinations revealed that the sodium citrate had been immobilised onto the magnetic nanoparticles. The highest water flux was obtained 17.1 L M⁻²h (LMH) per 80 g L⁻¹ osmotic agent solution against deionised water, while the ratio of salt flux to water flux was very low (0.088 g L⁻¹). The osmotic solution was evaluated for saline water desalination using different concentrations of sodium chloride (NaCl) as feed solutions. The average water fluxes of 6.2, 4.5, and 2.7 LMH was obtained for 0.1, 0.2, and 0.5 M salt solutions, respectively. The magnetic osmotic agent was separated by a magnet and re-used for several times without considerable decrease in the water flux.

GRAPHICAL ABSTRACT

KEYWORDS:

• Fe₃O₄ magnetic nanoparticles
• sodium citrate
• draw solution
• forward osmosis

Disclosure statement

No potential conflict of interest was reported by the author(s).