Adsorption of tetracycline by Nicandra physaloides (L.) Gaertn seed gum and Nicandra physaloides(L.) Gaertn seed gum/Carboxymethyl chitosan aerogel

ABSTRACT

In this study, novel aerogels of Nicandra physaloides (L.) Gaertn seed gum (NPG) and Nicandra physaloides (L.) Gaertn seed gum/Carboxymethyl chitosan (NPG/CMC) were prepared by freeze-drying method for removing tetracycline (TC) from water. Scanning electron microscope (SEM), X-ray diffraction (XRD),Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and Brunauer–Emmett–Teller (BET) were used to characterize structure and morphology of NPG and NPG/CMC aerogels. The average pore diameter of NPG and NPG/CMC were 3.04 and 1.2 nm, the specific surface areas were 2.67 and 0.73 m²/g, respectively. The maximum adsorption capacity of NPG and NPG/CMC aerogels for TC based on Langmuir isotherm was 266.7 and 332.23 mg/g respectively. Through thermodynamic and kinetic studies, it was found that the adsorption processes of the two adsorbents were spontaneous and followed the pseudo-second-order kinetic model. And the process of NPG adsorption of TC was endothermic, while NPG/CMC was exothermic.

GRAPHICAL ABSTRACT

KEYWORDS:

• Nicandra physaloides(L.) Gaertn seed gum
• Carboxymethyl chitosan
• Tetracycline
• Aerogels
• Adsorption

Data availability statement

All datas generated or analized during this study are included in this published article.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the National Natural Science Foundation of China: [Grant Number 51672140]; Taishan Scholar Program of Shandong Province: [Grant Number 201511029].