Immobilization of polypyrrole on waste face masks using a novel in-situ-surface polymerization method: removal of Cr(VI) from electroplating wastewater

ABSTRACT

In this work, polypyrrole (PPy) was synthesized on the surface of waste surgical face masks (SFM) with a novel environmentally-friendly in-situ-surface polymerization approach and used as an adsorbent for removing hexavalent chromium (Cr(VI)). In this method, the SFM surface was activated using KMnO₄, resulting in the immobilization of porous MnO₂, on which pyrrole can be polymerized efficiently. The novelty of this method is the presence of the oxidant on the surface before the polymerization step, which results in a better surface modification with polypyrrole. This method provides adsorbents with higher adsorption capacity compared to the conventional polymerization method with ammonium persulfate (APS). The adsorbent prepared at the mass ratios of 1.0 and 2.0; respectively, for KMnO₄/SFM and pyrrole/SFM showed the highest performance. The adsorbent characterization revealed the successful polymerization of pyrrole on the surface of SFM. Reusability of the KMnO₄ and pyrrole solutions were successful with remarkable results, showing the advantage of this technique compared to the conventional polymerization method with APS. The effect of different factors on the adsorption process was investigated. The removal rate was around 98% under the optimum conditions (pH, 2; adsorbent dosage, 3 g L⁻¹; contact time, 60 min). The equilibrium data were well fitted by Langmuir isotherm (R²=  0.9999). Kinetic investigations revealed that the adsorption process fitted well with the pseudo-second-order model. The adsorbent was regenerated for up to five cycles. One of the most important advantages of the proposed method compared to other methods is the reduction of wastewater during the synthesis process.

GRAPHICAL ABSTRACT

KEYWORDS:

• Adsorption
• hexavalent chromium
• polypyrrole
• removal
• surgical face mask

Acknowledgment

Thanks to the Nanotechnology Research Department of Environmental Engineering, Graduate Faculty of Environment, University of Tehran, Tehran, Iran, for supporting this research.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Data availability statement

The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.