The fate of Cu, Zn, Pb and Cd during the pyrolysis of sewage sludge at different temperatures

Abstract

In the present study, a sequential extraction procedure, recommended by the Community Bureau of Reference (BCR), was used for the fractionation of the heavy metals Cu, Zn, Pb and Cd in sewage sludge and its residues produced after pyrolysis at different temperatures from 250 to 700 °C. The results show that, in the sludge sample, the sum of the percentages of the reducible and oxidizable fractions for all metals except Cu was very high (65.4% for Cd, 85.7% for Pb, 78.7% for Zn), whereas the sum of the percentages of the oxidizable and residual fractions for Cu was very high (88.8%). The same result could be attained in the residues. Statistical analysis shows that at low temperatures the variation in pyrolysis temperature did not effectively contribute to the distribution of metal speciation in the residues. Meanwhile a modified Toxicity Characteristic Leaching Procedure (TCLP) was employed to determine the leachability of these four metals. The result indicates that the TCLP concentration of Cu, Zn, Pb and Cd dropped sharply after the temperature reached 350 °C, 550 °C, 500 °C and 400 °C respectively, which means pyrolysis can enhance the stability of these four metals when the temperature is high enough.

Keywords:

• sewage sludge
• residue
• pyrolysis
• metal speciation
• leachability

Acknowledgement

The project was supported by the National Natural Science Foundation of China (50908080 and 50878080), the Scientific and Technological Project of Hunan Province in China ([2008]GK3118) and by the Institute of Resource‐saving and Environment friendly Society in Hunan University (LXZD 200803).