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Original Articles

Influence of chitosan and epoxy cross-linking on physical properties of binary blends

, , , , &
Pages 163-174 | Received 14 Nov 2015, Accepted 09 Dec 2015, Published online: 19 Jan 2016
 

ABSTRACT

In this study, blends of chitosan (Cs) and bisphenol-F-diglycidyl ether (3.80 × 10−3 to 3.80 × 10−2 mol) were cast by the solution route. FT-IR results suggested that chitosan was cross-linked at terminal amino groups through diepoxide linkage. The chitosan films became less flexible and stiffer upon reaction with epoxy. Blending improved percentage elongation (31%) and toughness (10 MPa), whereas Young’s modulus (145 MPa) and tensile strength (45 MPa) were decreased. Extent of weight loss in Cs/BPFDGE was lower (15%) than that of original precursors (chitosan 33%). Moreover, blending of chitosan with BPFDGE increased water absorption properties due to generation of hydrophilic −OH groups.

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