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International Journal of Polymer Analysis and Characterization Volume 21, 2016 - Issue 3
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Original Articles

Solution properties of new “core-shell” structured polyorganosilsesquioxanes with two different types of “core-shell” surroundings

Alina I. AmirovaInstitute of Macromolecular Compounds of Russian Academy of Sciences, St. Petersburg, RussiaCorrespondence[email protected]
,
Olga V. GolubInstitute of Macromolecular Compounds of Russian Academy of Sciences, St. Petersburg, Russia
,
Dmitry A. MigulinN. S. Enikolopov Institute of Synthetic Polymer Materials of Russian Academy of Sciences, Moscow, Russia
&
Aziz M. MuzafarovN. S. Enikolopov Institute of Synthetic Polymer Materials of Russian Academy of Sciences, Moscow, Russia
Pages 214-220 | Received 04 Dec 2015, Accepted 25 Dec 2015, Published online: 01 Feb 2016
 
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ABSTRACT

Two “core-shell” structured polyorganosilsesquioxanes, differing in the arrangement of vinyl groups over the macromolecule volume, were studied in dilute solutions in toluene and ethyl acetate. It is shown that solution behavior is determined by the transposition of the functional vinyl groups in the core or shell of the macromolecule. This correlation is manifested in increasing the intrinsic viscosity values.

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