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International Journal of Polymer Analysis and Characterization Volume 24, 2019 - Issue 1
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Articles

Synthesis and hydrodynamic and conformation properties of star-shaped polystyrene with calix[8]arene core

Maria A. SimonovaInstitute of Macromolecular Compounds of the Russian Academy of Sciences, Saint Petersburg, Russia; Correspondence[email protected]
ORCID Iconhttp://orcid.org/0000-0001-5186-7876View further author information
ORCID Icon,
Elvira V. TarasovaDepartment of Materials and Environmental Technology, Tallinn University of Technology, Tallinn, EstoniaORCID Iconhttp://orcid.org/0000-0002-9904-629XView further author information
ORCID Icon,
Marina M. DudkinaInstitute of Macromolecular Compounds of the Russian Academy of Sciences, Saint Petersburg, Russia; ORCID Iconhttp://orcid.org/0000-0003-4263-8654View further author information
ORCID Icon,
Andrey V. TenkovtsevInstitute of Macromolecular Compounds of the Russian Academy of Sciences, Saint Petersburg, Russia; ORCID Iconhttp://orcid.org/0000-0002-3467-2740View further author information
ORCID Icon &
Alexander P. FilippovInstitute of Macromolecular Compounds of the Russian Academy of Sciences, Saint Petersburg, Russia; ORCID Iconhttp://orcid.org/0000-0002-8729-6275View further author information
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Pages 87-95 | Received 15 Oct 2018, Accepted 02 Dec 2018, Published online: 03 Jan 2019
 
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Abstract

Properties of individual molecules of star-like polystyrene with calix[8]arene core in dilute chloroform solutions were studied using methods of static light scattering, translation diffusion, and viscometry. The solution behavior of the polymer investigated significantly differs from the properties of linear polymers. Star-like polystyrene macromolecules in solutions are characterized by compact structure—the hydrodynamic radius is not higher than 5.5 nm at M = 125,000 g⋅mol−1. The shape of star-like polystyrene macromolecules differs slightly from spherical.

Disclosure of potential conflicts of interest

The authors declare that they have no conflict of interest.

Additional information

Funding

The work of Simonova M. A., Dudkina M. M., Tenkovtsev A. V. and Filippov A.P. was performed with the financial support of the Ministry of Science and Higher Education of the Russian Federation (project No AAAA-Ф 16-116071450046-9).

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