Abstract
Molecular Modelling of “spherical” cyclophosphazenic dandelion dendrimers shows that the whole moieties belong to the C3 point group, conversely to the starting material, N3P3Cl6, which is of D 3h symmetry. Moreover, these spherical dendrimers actually have significant dipole moments due to a non-centrosymmetrical distribution of the lone pairs of the nitrogen atoms of their amino groups and functions.