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Journal of Asian Natural Products Research Volume 13, 2011 - Issue 9
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Original Articles

Puberosides C–E, triterpenoid saponins from Glochidion puberum

Zhen Zhang State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Science, Kunming, 650204, China; College of Pharmacy, Dali University, Dali, 671000, China
,
Xin Fang State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Science, Kunming, 650204, China
,
Yue-Hu Wang State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Science, Kunming, 650204, China
,
Guang-Ming Liu College of Pharmacy, Dali University, Dali, 671000, China
,
Huai Xiao College of Pharmacy, Dali University, Dali, 671000, China
,
Xiao-Jiang Hao State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Science, Kunming, 650204, China
&
Hong-Ping He State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Science, Kunming, 650204, ChinaCorrespondence[email protected]
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Pages 838-844 | Received 21 Mar 2011, Accepted 14 Jun 2011, Published online: 10 Aug 2011
 
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Abstract

Three new triterpenoid glycosides, named puberosides C–E (1–3), were isolated from the water-soluble fraction of Glochidion puberum (Linn.) Hutch. Their structures were determined as 3α-[(O-β-d-glucopyranosyl-(1 → 3)-O-α-l-arabinopyranosyl)oxy]-22α-trans-cinnamoyl-olean-12-ene-16α,28-diol, 3α-[(O-β-d-glucopyranosyl-(1 → 3)-O-α-l-arabinopyranosyl)oxy]-22α-cis-cinnamoyl-olean-12-ene-16α,28-diol, and 3α-[(O-β-d-glucopyranosyl-(1 → 3)-O-β-d-glucopyranosyl)oxy]-22α-benzoyloxy-olean-12-ene-16α,28-diol by the combination of 1D, 2D NMR, and MS spectral analyses.

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