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Journal of Asian Natural Products Research Volume 18, 2016 - Issue 2
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A new bisabolane-type sesquiterpenoid from the fermentation broth of fungus Antrodiella gypsea

Zhen-Zhu ZhaoState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, China;University of Chinese Academy of Sciences, Beijing100049, ChinaView further author information
,
Li-Qiang HeState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, China;University of Chinese Academy of Sciences, Beijing100049, ChinaView further author information
,
He-Ping ChenState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, China;University of Chinese Academy of Sciences, Beijing100049, ChinaView further author information
,
Zheng-Hui LiState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, ChinaView further author information
,
Ze-Jun DongState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, ChinaView further author information
,
Tao FengState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, ChinaCorrespondence[email protected]
View further author information
&
Ji-Kai LiuState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650201, ChinaCorrespondence[email protected]
View further author information
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Pages 184-188 | Received 06 Feb 2015, Accepted 25 May 2015, Published online: 24 Jul 2015
 
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Abstract

Studies of the fermentation broth of fungus Antrodiella gypsea led to the isolation of a new bisabolane-type sesquiterpenoid that was named gypseatriol (1), together with the known compound 2,10-dodecadiene-1,6,7-triol (2). The structure of this new metabolite was assigned by analysis of 2D NMR and HR-EI-MS. Absolute configuration was assigned by single crystal X-ray diffraction analysis. Compound 1 was evaluated for its antifungal activity on Candida albicans.

Additional information

Funding

This work was financially supported by the Natural Science Foundation of Yunnan Province [grant number 2011FB099]; West Light Program of CAS [grant number 2013312D11016].

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