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Journal of Asian Natural Products Research Volume 21, 2019 - Issue 1
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Articles

Three new Lycopodium alkaloids from Lycopodium japonicum

Yu ZhuState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China;University of the Chinese Academy of Sciences, Beijing100049, China
,
Liao-Bin DongState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China
,
Zhi-Jun ZhangState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China;University of the Chinese Academy of Sciences, Beijing100049, China
,
Min FanState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China
,
Qin-Feng ZhuState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China;University of the Chinese Academy of Sciences, Beijing100049, China
,
Yan-Yan QiState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China;University of the Chinese Academy of Sciences, Beijing100049, China
,
Yu-Chen LiuState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China;University of the Chinese Academy of Sciences, Beijing100049, China
,
Li-Yan PengState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China
,
Xing-De WuState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, China
&
Qin-Shi ZhaoState Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming650204, ChinaCorrespondence[email protected]
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Pages 17-24 | Received 26 Oct 2017, Accepted 08 Jan 2018, Published online: 26 Jan 2018
 
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Abstract

Three new Lycopodium alkaloids (1–3), together with 15 known alkaloids, were isolated from club moss Lycopodium japonicum. Their structures were determined by extensive spectroscopic analysis, including 1D and 2D NMR spectra. Compound 1 has an unusual β-oriented methyl group substituted at C-15 and an α-hydroxy cyclopentenone moiety. All new alkaloids were evaluated for the inhibition of T-type calcium channel.

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