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Journal of Asian Natural Products Research Volume 8, 2006 - Issue 6
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3-Oxo-axisonitrile-3, a new sesquiterpene isocyanide from the Chinese marine sponge Acanthella sp.

X.-H. Yan Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research, Shanghai, 201203, China
,
X.-Z. Zhu Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research, Shanghai, 201203, China
,
J.-L. Yu Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research, Shanghai, 201203, China
,
D.-Z. Jin Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research, Shanghai, 201203, China
,
Y.-W. Guo Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research, Shanghai, 201203, ChinaCorrespondence[email protected]
,
E. Mollo Istituto di Chimica Biomolecolare del CNR, Puzzuoli (Na), 80072, Italy
&
G. Cimino Istituto di Chimica Biomolecolare del CNR, Puzzuoli (Na), 80072, Italy
 show all
Pages 579-584 | Received 30 Dec 2003, Accepted 10 Mar 2004, Published online: 17 Dec 2010
 
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Abstract

A new sesquiterpene isocyanide, 3-oxo-axisonitrile-3 (1), with a spiro [Citation5,Citation6] decane skeleton (spiroaxane) together with a known related sesquiterpene isonitrile (2), sesquiterpene isothiocyanates (3–8) and two diterpene isonitriles (9, 10) have been isolated from the Chinese marine sponge Acanthella sp. The structure of 1 has been determined on the basis of spectroscopic analysis.

Acknowledgements

This research was financially supported by “National Marine 863 Project (2001AA620403 and 2003AA624030)” and “National Natural Science Foundation for Outstanding Chinese Youths ” (no. 30125044).

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