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Original Articles

Synthesis of Y-type Polyurethanes Containing Novel NLO Chromophore

, &
Pages 309-319 | Received 21 Apr 2013, Accepted 27 Aug 2013, Published online: 13 Jun 2014
 

Abstract

Novel nonlinear optical chromophore with strong electron donor and isolation groups on both sides were synthesized and characterized by mass spectrum and hydrogen nuclear magnetic resonance. Electro-optical polymers with different chromophore loading densities were prepared and showed us good thermal stabilities, all of their thermal decomposition temperature were higher than 250°C. Large EO coefficients were also obtained by second harmonic generation method 29, 47, and 72 pm/V for PU-C10, PU-C15, and PU-C20, respectively. Solvatochromism of polymer PU-C10 was also studied; the result indicated us that this kind of polymers could be used as solvent polarity indicator material.

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