Tribological, Biomedical Studies of 4 Bromo–4' Chloro Benzylidene Aniline Macro-crystals for Photonic, Mechano, Electronic-displays and Pharma Applications

Abstract

The crystal of 4 Bromo − 4' Chloro Benzylidene Aniline-BCBA is synthesized and crystallized in the orthorhombic with Pccn space group. The lattice constants are a = 24.995 Å, b = 6.286 Å, c = 7.326 Å. The bond parameters are reported with statistics for the comparison purpose. The computational structural analyses about Vander Waal’s, 3D representation are portrayed; Raman spectroscopy provides the functional groups of BCBA. Mass spectrometer data reveal the molecular mass of BCBA as 295.5797; the Vander Waal’s type of interactions presented in the title compound, a systematic study of Super-cell, Laue’s model and Clinographic view of BCBA and device displays are carried out computationally. Hirshfeld surface analysis is used to envisage the many intermolecular interactions for the configuration of supramolecular structural design of BCBA. Dielectric properties are studied in the ambience of the room temperature for identifying the existence of all polarizations and in bio-medicinal use too as a better agent against diabetic macro level as IC₅₀ of 48.76 and 52.12 for alpha-amylase and alpha-glucosidase as in-vitro case; the wear and tear of BCBA-macro is better scaled up for tribological study with frictional coefficient as 3*10⁻³.

Keywords:

• FT-Raman
• Hirshfeld
• dielectric-macro
• devices
• displays

Acknowledgments

The authors would like to thank the IITM for XRD data and spectral data.

Author contributions

HG: conducted the research work and designed the experiment and corrected the manuscript; KSR: designed the study and visualization; MV: performed the optical studies and diagram corrections and clarity; KSK: grown the crystal, supervised the research work for structural case and over all write up; Also, all authors reviewed the manuscript.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Data availability statement

All the data is utilized and submitted in paper and no separate repository.

Additional information

Funding

No fund from any source and authors spent own funding.