Advanced search
Publication Cover
Polycyclic Aromatic Compounds Volume 44, 2024 - Issue 5
Submit an article Journal homepage
94
Views
0
CrossRef citations to date
0
Altmetric
Research Articles

A New Approach to the Ring-Opening of Epoxides under Mild and Green Conditions

Ali Reza Ataee-Najaria Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, IranView further author information
,
Mahmoud Zareib Department of Chemistry, Faculty of Science, University of Qom, Qom, IranCorrespondence[email protected]
View further author information
,
Hossein Ahmadia Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, IranView further author information
,
Mohammad Ali Zolfigola Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, IranCorrespondence[email protected] [email protected]
View further author information
,
Arash Ghorbani-Choghamarania Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, IranCorrespondence[email protected]
View further author information
&
Mojtaba Hosseinifardc Department of Energy, Materials and Energy Research Center, Karaj, IranView further author information
Pages 3442-3455 | Received 03 Nov 2022, Accepted 28 Jun 2023, Published online: 20 Jul 2023
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

In this research work, we have designed and introduced [Zr-UiO-66-CO2H]Br as a versatile heterogeneous acid catalyst for the ring-opening of epoxides through SN1 and/or SN2 type mechanisms. In addition, the appropriate method for designing an active and efficient Bronsted acid site in metal-organic frameworks is discussed. [Zr-UiO-66-CO2H]Br was applied for the preparation of α-aryloxy alcohols by the condensation reaction of various epoxides with phenol or thiophenols under mild and green conditions.

Graphical abstract

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

We thank Bu-Ali Sina University and Iran National Science Foundation (INSF) [grant number: 98001912] for financial support to our research group.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 1,492.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.