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Original Articles

DITHIOPHOSPHORIC ACIDS AND TETRAPHOSPHORUS DECASULFIDE IN THE SYNTHESIS OF BORON DITHIOPHOSPHATES

, , , &
Pages 157-166 | Received 06 Jul 1999, Published online: 04 Oct 2006
 

Abstract

The reactions of O,O-dialkyl dithiophosphoric acids with triisobutyl borate, ammonium O,O-diisobutyl dithiophosphate with fluorodiisobutyl borate, and tetraphosphorus decasulfide with triisobutyl borate were studied. On the basis of these studies, new boron derivatives of dithiophosphoric acids were obtained. Low frequency ultrasonic irradiation (22 kHz, power 130 W) leads to reduction in reaction temperature and time in the reactions studied.

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