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Original Articles

SOLID-PHASE OXIDATION OF ORGANIC COMPOUNDS WITH BENZYLTRIPHENYLPHOSPHONIUM DICHROMATE

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Pages 145-151 | Received 30 Dec 1999, Accepted 19 Mar 2000, Published online: 27 Oct 2006
 

Abstract

Benzyltriphenylphosphonium dichromate could be used for oxidation of organic compounds such as alcohols, thiols and sulfides to the corresponding carbonyl, disulfide and sulfoxide derivatives under solid-phase conditions. This reagent is very easily prepared from an aqueous solution of benzyltriphenylphosphonium chloride with CrO3 in 3 N HCI at room temperature. The reagent, is a stable orange powder, which may be stored for month without loss of its activity.

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