Synthesis of Novel Maleonitrile Derivatives

Abstract

The synthesis of four novel maleonitrile derivatives are described. New maleonitriles have been prepared by the reaction of different alkylhalides such as 3-bromopropionitrile, 1,3-dichloroacetone, α, α′-dibromoxylene, and p-nitrobenzylbromide with dithiomaleonitrile disodium salt. All novel compounds have cis-cyano groups and are characterized by IR, NMR spectroscopy, and elemental analysis.

This work was supported by the Research Fund of İstanbul Technical University.

KeyWords :

• Cyclophane
• ligands
• macrocycle
• maleonitrile
• porphyrazine

Notes

This work was supported by the Research Fund of İstanbul Technical University.