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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 179, 2004 - Issue 1
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Original Articles

HYDROSILYLATION OF AROMATIC AZOMETHINS

Vjacheslav V. Zuev Institute of Macromolecular Compounds, Russian Academy of Sciences, Sankt Petersburg, Russian Federation
,
Olga P. Kovaleva Department of Synthetic Rubbers and Organoelement, Compounds of Sankt Petersburg, State Technological Institute (Technical University), Sankt Petersburg, Russian Federation
&
Nikolai K. Skvortsov Department of Synthetic Rubbers and Organoelement, Compounds of Sankt Petersburg, State Technological Institute (Technical University), Sankt Petersburg, Russian Federation
Pages 83-88 | Received 01 Apr 2003, Accepted 01 Jul 2003, Published online: 11 Aug 2010
 
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Abstract

The interaction of aromatic azomethins with methyldichlorosilane, phenyldichlorosilane, and dimethylchlorosilane has been investigated in the presence of a Speier catalyst, a Wilkinson catalyst, a Karsted catalyst, and a range of LL'PtCl 2 complexes. The reaction yielded the products of hydrosilylation and reduction as identified by 1 H NMR. The ratio of hydrosilylation/reduction products depends of the catalyst used. The higher yield of hydrosilylation products was observed with using Pt(II) complexes as a catalyst.

Notes

∗DESO-diethylsulfoxide.

1 Yields was determined using of 1H NMR spectroscopy.

∗DESO-diethylsulfoxide.

1 Yields was determined using of 1H NMR spectroscopy.

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