FROM 1,3-DIPHOSPHETANE-2,4-DIYLS TO CYCLIC ANIONS AND CATIONS

Abstract

The interest in diradicals has grown by the increasing number of stable diradicals which have been synthesized during the last few years. The diphosphacyclobutane-diyles have a diradicaloid molecular structure and they were the first diradicals to be prepared in the gramme scale. The combination of stability and high yield synthesis creates the opportunity both to change the substitution pattern or to prepare different valence isomers. Current experimental and computational studies reveal that electron transfer reactions of maintain the cyclic system. In the contribution, the oxidation reaction of 1 to the radical cation 2 and the cyclic diphosphaallyl cation 3 will be reported. Additionally, the remarkable mechanism of the reaction of 1 at first to the radical anion 4 but particularly to the diphosphacyclobutadiene dianion 5 under reductive conditions will be presented in detail.

Keywords:

• Diphosphallyl cations
• diphosphetane diyls
• diradicals

Notes

*EPR-measurements were carried out by A. Elvers, U. Zenneck, Universität Erlangen.