New N,S-Substituted Dienes from Mono(thio)substituted-2-nitrohalo-1,3-diene and Some Amines

Mono(thio)substituted nitrodiene compound 1 reacted with 2a–f and yielded 3a–f in methylene chloride. Compound 1 gave 7 by the reaction with 6. Compounds 5a–c were obtained by the reactions of 4a–c with 1. 3a also has been structurally characterized using single-crystal X-ray diffraction analyses.

Keywords:

• 2-Nitrohalodiene
• 4-methoxythiophenol
• mono(thio)substituted nitrodiene
• N,S-substituted nitrodiene
• piperazine
• piperidine
• thiosubstituted halodiene

Acknowledgments

We thank the Research Fund of Istanbul University for financial support of this work.