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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 181, 2006 - Issue 6
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Original Articles

A Polysulfide Based on Bis(thien-2-yl)sulfide: Synthesis and Testing as an Active Cathode Material

Galina F. Myachina A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
,
Svetlana A. Korzhova A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
,
Lyubov K. Papernaya A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
,
Eleonora N. Deryagina A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
,
Terje A. Skotheim Moltech Corporation, Tucson, USA
&
Boris A. Trofimov A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
Pages 1241-1247 | Received 05 Jan 2005, Accepted 10 Jan 2006, Published online: 01 Feb 2007
 
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A reaction of the polycondensation product of bis(thien-2-yl)sulfide and formaldehyde with elemental sulfur affords a polymer containing polysulfide moieties (S-content = 67.2%). When used as active cathode material for model lithium rechargeable cells, the polymer shows the discharge capacity of 620 mA·h· g−1 at the first cycle.

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