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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 182, 2007 - Issue 3
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Original Articles

A New Method for the Synthesis of Isothiocyanates from Dithiocarbamates or Alkyl Amines Using Chlorosilanes as Decomposition Reagents

Gaofeng Bian Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, Hangzhou, Zhejiang, P.R. China
,
Huayu Qiu Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, Hangzhou, Zhejiang, P.R. China
,
Jianxiong Jiang Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, Hangzhou, Zhejiang, P.R. China
,
Jirong Wu Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, Hangzhou, Zhejiang, P.R. China
&
Guoqiao Lai Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Teachers College, Hangzhou, Zhejiang, P.R. China
Pages 503-508 | Received 04 Apr 2006, Accepted 27 Jul 2006, Published online: 30 Jan 2007
 
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Abstract

A series of isothiocyanates were prepared in good yields by the decomposition of dithiocarbamates using chlorosilanes such as Me 3 SiCl, Me 2 SiCl 2 , MeSiCl 3 , and SiCl 4 as decomposition reagents. Alkyl isothiocyanates were obtained by a facile one-pot method in high yield from alkyl amines using these inexpensive decomposition reagents in the presence of a base.

Acknowledgments

This project was supported by the Key Project of Ministry of Education of China (No. 03053) and by the Scientific Research Fund (No. 20050722) of the Education Department of Zhejiang Province.

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