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Abstract
Reactions of N-bromosuccinimide with ammonium salt of alkylene (dialkyl) dithiophosphates; [
; G = ─CMe
2
CMe
2
─CH
2
CMe
2
CH
2
-, CMe
2
CH
2
CHMe-, CH
2
CH
2
CHMe-; (RO)
2
PS
2
NH
4
; R = C
2
H
5
, n-C
3
H
7
, i-C
3
H
7
] in 1:1 molar ratio in refluxing benzene solution yields red/brown-colored sticky liquids. These newly synthesized complexes have been characterized by physicochemical and spectroscopic techniques (MW, IR, and NMR [
1
H and
31
P]). The computational semi-empirical calculations (MOPAC6P/c) have also been studied for these complexes. On the basis of above studies, the formation of P-S-N chemical linkage has been established.