Abstract
Phenylarsenic(III) Dimethoxide reacts with N-/S- alkyl of 2-aminocyclopentene 1- carbodithioic acid and its nitrogen-/sulfur-alkyl derivatives in 1:2 and 1:1 molar ratio yields some new complexes and addition complexes of the type: where R′ = ─H,─CH 3 ,─C 2 H 5 ,─C 4 H 9 and R = ─CH 3 and CH 2 N(C 2 H 5 ). Reactants were mixed in 1:1 and 1:2 molar ratios and the resulting mixture was refluxed for 5 to 6 h to ensure completion of the reaction. Sodium chloride precipitated was filtered off. Yellow to dark brown colored solids were isolated; these complexes were found to be soluble in common organic solvents (e.g., CHCl 3 , etc.) These complexes and additional complexes have been characterized by physicochemical and spectroscopic studies.
Notes
∗After recrystallization.