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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 183, 2008 - Issue 2-3
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Original Articles

Functionalized Phosphoryl Compounds: Synthesis, Extraction, Transport and Ionophore Properties

R. A. Cherkasov Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
,
A. R. Garifzjanov Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
,
N. S. Krasnova Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
,
A. S. Talan Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
,
G. Z. Badretdinova Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
,
L. M. Burnaeva Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
&
G. A. Ivkova Kazan State University, A.M. Butlerov Chemistry Institute, Kazan, Russia
 show all
Pages 406-409 | Published online: 20 Jun 2008
 
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Abstract

The row of phosphoryl compounds, having additional functional groups with complexating abilities were synthesized via the classical methods of the organophosphorus chemistry. The extraction properties of the mono- and biphosphorilated amines were investigated and it is shown the high efficiency and selectivity of the noble metal ions extraction from acid water solutions. Some phosphorylated azapodands were obtained by Kabachnik–Fields reaction and their membrane transport and ionophoric properties were investigated.

Acknowledgments

The work is supported by the Russian Foundation for Basic Research (grant No 07-03-00306), joint program of CRDF and Russian Ministry of Education “Basic Research and High Education” (REC 007).

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