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Original Articles

Gold(I) Phosphine Complexes Containing Selenocarbamate Esters: Crystal and Molecular Structure of N-phenyl-O-methylselenocarbamate

, &
Pages 1050-1056 | Published online: 29 Oct 2008
 

Abstract

A series of both mono- and dinuclear gold(I) phosphine complexes containing deprotonated N-phenyl-O-methylselenocarbamate of the type [AuSeC(OMe) = NPh(P)] and [Au 2 SeC(OMe) = NPh 2 (PP)] (P = PPh 3 , P(o-tolyl) 3 , PTA; PP = dppm, dppe, dppp, dppf) were prepared and characterized by spectroscopic techniques. The X-ray crystal structure of SeC(OMe)═N(H)Ph is also reported and shows the molecule to exist in the E-conformation. Centrosymmetrically related dimers associate in the crystal structure by N─H…Se interactions.

Acknowledgments

We thank the Fonds der Chemischen Industrie as well as the University of Wuppertal for generous financial support of this work.

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