Abstract
Hexachlorobutadiene 1 reacts with 3-mercapto-1-hexanol in water-ethanol mixture in the presence of sodium hydroxide to give the new monosubstituted thioether 3-(perchlorobuta-1,3-dienyl-thio)-hexan-1-ol 3a and the disubstituted thioether 3,3′ -(perchlorobuta-1,3-diene-1,4-diyl) bis(sulfane-diyl)-dihexan-1-ol 4a . 1-Chlorohexan-3-yl-pentachlorobutadienyl-sulfide 5a , 2-chloroethyl-penta-chlorobutadienyl-sulfide 5b , 2-chloropropyl-pentachlorobutadienyl-sulfide 5c and 1,2,3,4-tetra-chlorobuta-1,4-bis(2-chloroethylsulfanyl)-buta-1,3-diene 6b were obtained from the reaction of 3a–c and 4b with SOCl2 in pyridine. The derivatives 8b–k and 9a were synthesized from the reaction of componds 5b and 5c in water-ethanol mixture in the presence of sodium hydroxide with the corresponding thiol, respectively.
Acknowledgments
We thank the Research Fund of the University of Istanbul for financial support of this work.