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Original Articles

Synthesis and Characterization of Chloropentaaryloxycyclotriphosphazene Derivatives

, , , &
Pages 2103-2108 | Received 08 Jul 2008, Accepted 20 Aug 2008, Published online: 22 Jul 2009
 

Abstract

Five chloropentaaryloxycyclotriphosphazene derivatives were synthesized by the reaction of hexachlorocyclotriphosphazene with potassium phenoxide in tetrahydrofuran. A satisfactory yield could be obtained when a 5.1 : 1(KOC 6 H 4 R : P 3 N 3 Cl 6 ) molar ratio was used. The new compounds were characterized by IR, 1H NMR, 31P NMR, 13C NMR, and ESI-MS, and for two of them by HR-MS.

The authors would like to thank the National Natural Science Foundation of China (No. 20602032, 20732004) and Zhengzhou University for financial support.

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