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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 184, 2009 - Issue 11
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Original Articles

A Convenient Synthesis of Novel Phosphoramide Mustard Analogues of 2-Arylquinolone

Jinwei Yuan Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Xiaolan Chen Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Lingbo Qu Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China; Henan University of Technology, Henan Province, Zhengzhou, P. R. China
,
Shouren Zhang Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Jiansha Lu Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
&
Yufen Zhao Key Laboratory of Organic Chemistry and Chemical Biology, Henan Province, Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China; Key Laboratory for Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Department of Chemistry, School of Life Sciences and Engineering, Tsinghua University, Beijing, P. R. China
Pages 2936-2944 | Received 12 Sep 2008, Accepted 13 Nov 2008, Published online: 03 Nov 2009
 
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Abstract

A series of novel phosphoramide mustard analogues of 2-arylquinolones are synthesized through a convenient and facile phosphorylated reaction, and their structures are elucidated by NMR, IR, and HR MS. The amino acid esters and phosphoryl nitrogen mustard are linked to 2-arylquinolone to improve their undesirable physicochemical and biological properties.

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