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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 184, 2009 - Issue 4: Honoring the 70th Birthday of Marian Mikolajczyk
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Original Articles

Unprecedented C-Acylation of Imines with Tervalent Phosphorus Isocyanates

Yu. V. Rassukana Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine
,
P. P. Onys'ko Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine
,
A. I. Arkhypchuk Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine
&
A. D. Sinitsa Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine
Pages 992-997 | Received 28 Dec 2007, Accepted 18 Feb 2008, Published online: 26 Mar 2009
 
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Abstract

Reaction of trifluoropyruvate N-phosphorylimine with tervalent phosphorus isocyanates leads to unexpected acylation of the imine carbon atom to afford phosphorylaminocarbonylated trifluoroalanine derivatives.

Dedicated to Professor Marian Mikołajczyk from the CBMiM PAN in Łódź, Poland, on the occasion of his 70th birthday.

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