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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 184, 2009 - Issue 5: Honoring the 70th Birthday of Marian Mikolajczyk, Part 2
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Original Articles

The Behavior of 4-Azidocoumarin-3-carboxaldehyde Towards Certain Sulfur Reagents and Primary Amines

Nabila M. Ibrahim Department of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Cairo, Egypt
,
Hisham Abdallah A. Yosef Department of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Cairo, Egypt
,
El-Sayed M. A. Yakout Department of Pesticide Chemistry, National Research Centre, Dokki, Cairo, Egypt
&
Mohamed Refat H. Mahran Department of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Cairo, Egypt
Pages 1124-1138 | Received 21 Nov 2007, Accepted 25 Feb 2008, Published online: 28 Apr 2009
 
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Abstract

The behavior of 4-azidocoumarin-3-carboxaldehyde ( 1 ) towards certain sulfur reagents such as isothiocyanates ( 2a–c ), thionyl chloride, Lawesson's reagent (LR, 3 ), and phosphorus pentasulfide as well as towards primary amines such as glycine ( 4 ) and towards anthranilic acid ( 5 ) was investigated. The structures of the new products were attested by suitable analytical and spectroscopic measurements.

Dedicated to Professor Marian Mikołajczyk, CBMiM PAN in Łódź, Poland, on the occasion of his 70th birthday.

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