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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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I. Synthesis and Applications in Catalysis

Green Chemical Tools in Organophosphorus Chemistry—Organophosphorus Tools in Green Chemistry

György Keglevich Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Alajos Grün Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary; Research Group for Organic Chemical Technology, Hungarian Academy of Sciences, Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Erika Bálint Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Nóra Zs. Kiss Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Rita Kovács Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
István G. Molnár Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Zsófia Blastik Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
R. Viola Tóth Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
András Fehérvári Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
&
István Csontos Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
 show all
Pages 613-620 | Received 26 May 2010, Accepted 07 Jul 2010, Published online: 25 Apr 2011
 
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Abstract

A variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave MW-assisted and solventless conditions, occasionally in ionic liquids (ILs). In a few cases, MW was synergic with phase transfer catalysis or could substitute it. A variety of P(III) ligands were developed and converted to Pt(II) complexes that can be used as catalysts. Finally, phosphorylations and the Kabachnik–Fields reaction were monitored and optimized by an on-line method, in situ Fourier transform IR spectroscopy.

Acknowledgments

Support from the Hungarian Scientific Research Fund (OTKA No. K83118) is acknowledged.

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