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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 5: 24th International Symposium on the Organic Chemistry of Sulfur
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Oral Contributions

Highly Stereoselective Construction of Multiple Stereogenic Centers Using Allylic Sulfides

Takeshi Takeda Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
,
Dr Yasutaka Yatsumonji Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
,
Mr Takuya Nishimura Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
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Mr Takenori Sugita Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
&
Dr Akira Tsubouchi Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
Pages 1229-1233 | Received 17 Jun 2010, Accepted 07 Jul 2010, Published online: 12 Jul 2011
 
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Abstract

A new methodology for the construction of multiple stereogenic centers by the reaction of ketones with allyltitanium reagents generated by the reductive titanation of allylic sulfides is described.

Acknowledgments

This research was supported by a Grant-in-Aid for Scientific Research (No. 21350026) from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

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