66
Views
0
CrossRef citations to date
0
Altmetric
Oral Contributions

Chalcogen Halides Plus Propargyl Alcohols—Fascinating Reaction Pathways and Products

, , , &
Pages 1251-1254 | Received 30 Jun 2010, Accepted 07 Jul 2010, Published online: 12 Jul 2011
 

Abstract

A convenient method to incorporate selenium into an organic molecule is reported. Selenium halides undergo smooth 1,2-addition to the triple bond of various propargylic alcohols under mild reaction conditions and with complete regio- and stereospecificity. The products arising from these reactions depend on the nature of the selenium halide as well as on the substitution pattern of the propargyl alcohol. Of special mechanistic interest is the syn-addition and anti-Markovnikov orientation observed in all cases.

Acknowledgments

This work was supported by a grant from the Israel Science Foundation (Grant No. 919-05).

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 2,235.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.