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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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I. Synthesis and Applications in Catalysis

Imidoylphosphonates-Alkylideneaminophosphonates Interconversions via Biomimetic Transamination Reaction

P. P. Onys’ko Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine
,
T. V. Kim Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine
,
O. I. Kyselyova Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine
,
Yu. V. Rassukana Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine
&
A. D. Synytsya Institute of Organic Chemistry, NAS of Ukraine, Kyiv, Ukraine
Pages 721-728 | Received 26 Jul 2010, Accepted 30 Aug 2010, Published online: 25 Apr 2011
 
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Abstract

The data on prototropy in imidoylphosphonates containing α-hydrogen atoms in the N-alkyl group of the C˭N bond were systematized and generalized. Imidoylphosphonates-alkylideneaminophosphonates interconversions via biomimetic transamination reaction are in main focus of the review. Central to this endeavor is the elucidation of the effect that the phosphonyl moiety exerts on prototropy in the phosphorylated 2-azaallylic triad.

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