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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 7
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Regular Articles

Synthesis and Characterization of Novel Alkyl-Substituted Aryl Diphenylphosphinate Esters

Saliha Begeç Department of Chemistry, Science and Arts Faculty, Inonu University, Malatya, Turkey
,
Sümeyya Alataş Department of Chemistry, Science and Arts Faculty, Inonu University, Malatya, Turkey
&
Adem Kılıç Department of Chemistry, Gebze Institute of Technology, Gebze, Kocaeli, Turkey
Pages 1531-1537 | Received 30 Apr 2010, Accepted 31 Aug 2010, Published online: 04 Aug 2011
 
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Abstract

In this work, the reactions of diphenylphosphinic chloride, (C6H5)2P(O)Cl, 1, with the sodium salts of sterically hindered phenol derivatives (2a-2j) were investigated. Novel alkyl-substituted aryl diphenyl phosphinate esters (C6H5)2P(O)OAr (3-12) were obtained from these reactions. Satisfactory analytical and spectroscopic results were obtained for all the new compounds.

GRAPHICAL ABSTRACT

Acknowledgments

We thank the Inönü University Research Fund for partial financial support (Project No: 2008/49).

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