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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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I. Synthesis and Applications in Catalysis

Synthesis and Reactivity of an 1,3-Oxazin-6-one Derived from α-Aminophosphonate

Francisco Palacios Departamento de Química Orgánica I, Facultad de Farmacia, Universidad del País Vasco, UPV/EHU, Vitoria-Gasteiz, Spain
,
Edorta Martínez de Marigorta Departamento de Química Orgánica I, Facultad de Farmacia, Universidad del País Vasco, UPV/EHU, Vitoria-Gasteiz, Spain
,
Marta Rodríguez Departamento de Química Orgánica I, Facultad de Farmacia, Universidad del País Vasco, UPV/EHU, Vitoria-Gasteiz, Spain
&
Carmen Vinagre Departamento de Química Orgánica I, Facultad de Farmacia, Universidad del País Vasco, UPV/EHU, Vitoria-Gasteiz, Spain
Pages 729-734 | Received 21 Jul 2010, Accepted 03 Sep 2010, Published online: 25 Apr 2011
 
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Abstract

A synthetic route for a phosphorylated 1,3-oxazin-6-one has been described, its reactivity towards nucleophiles and heterodienophiles has been assessed, and new α-dehydro-aminophosphonate derivatives are obtained.

Acknowledgments

The authors thank The University of the Basque Country (UPV/EHU, GIU 09/56); the Departamento de Educación, Universidades e Investigación del Gobierno Vasco (GV, Vitoria, IT-422-10); and the Dirección General de Investigación del Ministerio de Ciencia y Tecnología (MICICN, Madrid DGI, CTQ2009-12156) for supporting this work. M. Rodríguez thanks the Dirección General de Enseñanza Superior e Investigación Científica (Madrid) for a predoctoral fellowship.

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