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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 4: 18th International Conference on Phosphorus Chemistry (ICPC2010)
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IV. Biologically Relevant Organophosphorus Compounds

Evaluation Of Single-Stranded Oligonucleotide Cleavage Function Of Seryl-Histidine Dipeptide By Electrospray Ionization Mass Spectrometry

Pei-yan Chen The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China
,
Yan Liu The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China
,
Xiang Gao The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China
,
Niu-sheng Xu Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun Center of Mass Spectrometry, Changchun, P. R. China
,
Jun Niu Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun Center of Mass Spectrometry, Changchun, P. R. China
,
Shu-ying Liu Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun Center of Mass Spectrometry, Changchun, P. R. China
&
Yufen Zhao The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China
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Pages 933-935 | Received 13 Sep 2010, Accepted 19 Sep 2010, Published online: 25 Apr 2011
 
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Abstract

The cleavage action of Ser-His on a series of single-stranded oligonucleotides was investigated by Fourier-transform ion cyclotron resonance mass spectrometry with electrospray ionization. It was found that polyadenine was selectively hydrolyzed at the terminal phosphodiester bond.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20732004, 20805037) and the Research Fund for the Doctoral Program of Higher Education of China (No. 200803841009).

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