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Communications

The Reaction of Cyclopropanols with Burgess Reagent: A Reinvestigation and Correction

, &
Pages 205-212 | Received 21 Sep 2010, Accepted 08 Oct 2010, Published online: 19 Feb 2011
 

Abstract

The reaction of cyclopropanols with Burgess reagent yields the unusual sulfamates 8 and their N-methylated derivatives 9. Unlike a previous study, dicyclopropyl ether formation was not observed. Also, the mechanism of ether formation from a cyclopropanol precursor cannot follow an SN2 pathway with retention.

GRAPHICAL ABSTRACT

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