New Organotin Compounds Including a Tin–Zinc Bond

Abstract

The reaction of dialkyltinhydrides with dialkylzinc results in a tin metal bond formation. Crystal structures of 1,1,1,2,3,3,3-hepta-phenyl-2-(ethylzincio)tristannane *TMEDA 1, 1,1,2,2,3,3,4,4-octaphenyl-1,4-(ethylzincio)tetrastannane*2TMEDA 2, and triphenyl(phenylzincio)stannane*TMEDA 3 could be obtained.

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GRAPHICAL ABSTRACT

Keywords:

• Crystal structure
• diethylzinc
• tinhydrides
• zinc metal bond

Acknowledgments

The financial support of this work by fForte-Wissenschaftlerinnenkolleg FreChe Materie is acknowledged. Prof. Albering is acknowledged for crystal structure solving.