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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 186, 2011 - Issue 11
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Original Articles

Synthesis of Novel Thioethers from Polyhalobutadienes and Thiols

Nihal Onul Division of Organic Chemistry, Department of Chemistry, Faculty of Engineering, Istanbul University, 34320, Avcilar, Istanbul, Turkey
,
Wafaa M. Dib Brimo Division of Organic Chemistry, Department of Chemistry, Faculty of Engineering, Istanbul University, 34320, Avcilar, Istanbul, Turkey
&
Cemil Ibis Division of Organic Chemistry, Department of Chemistry, Faculty of Engineering, Istanbul University, 34320, Avcilar, Istanbul, Turkey
Pages 2180-2188 | Received 08 Feb 2011, Accepted 19 Apr 2011, Published online: 31 Oct 2011
 
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Abstract

Substituted perchlorobutadienes were synthesized from the reactions of hexachloro-1,3-butadiene with some thiols in ethanol in the presence of sodium hydroxide. The oxidation products were obtained from the reactions of thioethers with m-chloroperbenzoic acid. The structures of the new compounds were characterized by microanalysis and spectroscopic data.

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