Electron Ionization Mass Spectra of Organophosphorus Compounds. Part III: Mass Spectrometric Fragmentation of Diethyl Spiro[Pyrimidino[5,3′][1,2]Oxazole] Phosphonate, Diethyl (Oxazolo[5,4-D]Pyrimidine-4,6-Dione)Phosphonate, and Diethyl (Pyrimidino[4,5-B][1,4]Oxazine)Phosphonate Derivatives

Abstract

Fragmentation pathways of 14 organophosphorus compounds derived from diethyl spiro[pyrimidino[5,3][1,2]oxazole] phosphonates, diethyl (oxazolo[5,4-d]pyrimidine-4,6-dione)phosphonates, and diethyl (pyrimidino[4,5-b][1,4] oxazine)phosphonates were investigated by electron impact mass spectrometry (EI-MS). The intensity of the recorded molecular ion peaks showed various values depending on the nature of the compounds. Characteristic fragment ions were formed by successive loss of simple functional groups followed by decomposition of heterocycles connected to pyrimidine rings.

GRAPHICAL ABSTRACT

Keywords:

• Mass spectrometry
• fragmentation processes
• organophosphorus
• spiro [pyrimidino[5,3′][1,2]oxazole]phosphonate
• (oxazolo[5,4-d]pyrimidine-4,6-dione) phosphonate
• (pyrimidino[4,5-b][1,4]oxazine)phosphonate