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Original Articles

Coordination Features of P,S-Ligands Based on the Phosphorus Derivatives with I and Viii Group Metals

, , , , &
Pages 490-492 | Received 06 Jul 2012, Accepted 02 Aug 2012, Published online: 29 May 2013
 

Abstract

Continuing the study of the coordination ability of P,S-ligands, we have investigated the behavior of some P(IV)-S-phosphorus derivatives, in particular, trialkyltetrathiophosphates (R = i-Pr, Bu) and piperidinium and triethylammonium salts of octathiotetraphosphetane in reaction with Cu(I), Ag(I), Co(II), and Fe(II) halides. The series of complexes were obtained and characterized by the X-ray single crystal diffraction and IR/Raman spectroscopy.

GRAPHICAL ABSTRACT

Acknowledgments

Financial supports from the RFBR (No 09-03-00006-а and No 12-03-00479-а) and DCSM RAS (Program 6) are gratefully acknowledged.

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