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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 188, 2013 - Issue 1-3: 19th International Conference on Phosphorus Chemistry (ICPC-2012) Rotterdam, 8–12 July, 2012
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Original Articles

Novel Biomimetic Cyclic P,N-Ligands. Lability of P-CH2-N Fragment: Problem or Advantage?

Andrey A. Karasik Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia
,
Elvira I. Musina Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia
,
Anna S. Balueva Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia
&
Oleg G. Sinyashin Laboratory of Organometallic and Coordination Compounds, A. E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS, Kazan, Russia
Pages 27-28 | Received 16 Jul 2012, Accepted 15 Oct 2012, Published online: 08 May 2013
 
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Abstract

The lability of the P-CH2-N fragment results in thermodynamically controlled processes of stereoconversions, substituents exchange, and ring transformations of P,N-containing hetero- and macrocycles.

GRAPHICAL ABSTRACT

Acknowledgments

This work was supported by RFBR (No. 10–03-00380-а, 11–03-12152-ofi_m), the President's of RF grant for leading scientific schools (No. NSh-6667.2012.3), and the VW Foundation (No. 85 625).

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