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Original Articles

Resolution of 5- and 6-Membered P-Heterocycles: Racemic and Optically Active Platinum(II)-3-Phospholene Complexes

, , , , &
Pages 36-38 | Received 16 Jul 2012, Accepted 14 Oct 2012, Published online: 08 May 2013
 

Abstract

Methods were developed for the resolution of several five- and six-membered phosphorus heterocycles (1c-e, 2, 4). It was investigated if the optical activity is preserved during the 1a→2→3→4 reaction sequence. Racemic and optically active 1b-e 3-phospholene 1-oxides were converted to the corresponding platinum-complexes (10b-e), which are potential catalysts.

GRAPHICAL ABSTRACT

Acknowledgments

This project was partially supported by the Hungarian Scientific Research Fund (OTKA K83118).

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