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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 8: 26th International Symposium on Organic Chemistry of Sulfur (ISOCS-26)
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Original Articles

Aziridines Ring Opening by Silyl Chalcogenides: a Stereoselective Access to Polyfunctionalized Molecules as Precursor of Sulfurated and Selenated Heterocycles

Damiano TaniniDipartimento di Chimica “Ugo Schiff”, University of Florence, Via della Lastruccia3-13, 50019, Sesto Fiorentino, ItalyCorrespondence[email protected]
,
Giulia BarchielliDipartimento di Chimica “Ugo Schiff”, University of Florence, Via della Lastruccia3-13, 50019, Sesto Fiorentino, Italy
,
Francesca BenelliDipartimento di Chimica “Ugo Schiff”, University of Florence, Via della Lastruccia3-13, 50019, Sesto Fiorentino, Italy
,
Alessandro Degl’InnocentiDipartimento di Chimica “Ugo Schiff”, University of Florence, Via della Lastruccia3-13, 50019, Sesto Fiorentino, Italy
&
Antonella CapperucciDipartimento di Chimica “Ugo Schiff”, University of Florence, Via della Lastruccia3-13, 50019, Sesto Fiorentino, Italy
Pages 1265-1270 | Received 10 Nov 2014, Accepted 21 Dec 2014, Published online: 03 Aug 2015
 
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GRAPHICAL ABSTRACT

Abstract

Aziridines react efficiently with bis(trimethyl)silyl-sulfide and -selenide to afford a direct access to β-amino thiols and selenols. Synthesis of 2,4-disubstituted 1,3-selenazolidines is obtained through reaction of 1,2-amino selenols with aldehydes.

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