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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 10
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Original Articles

Imidazole Promoted Highly Efficient Large-Scale Thiol-Free Synthesis of Symmetrical Disulfides in Aqueous Media

Babak MokhtariChemistry Department, Faculty of Science, Shahid Chamran University of Ahvaz, 61357-43169, Ahvaz, IranCorrespondence[email protected]
,
Ali Reza KiasatChemistry Department, Faculty of Science, Shahid Chamran University of Ahvaz, 61357-43169, Ahvaz, Iran
&
Javid MonjeziChemistry Department, Faculty of Science, Shahid Chamran University of Ahvaz, 61357-43169, Ahvaz, Iran
Pages 1573-1579 | Received 08 Dec 2014, Accepted 29 Dec 2014, Published online: 02 Sep 2015
 
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GRAPHICAL ABSTRACT

Abstract

A highly efficient and environmentally friendly method for the imidazole promoted preparation of symmetrical organic disulfides from Bunte salts is described. This thiol-free procedure produces the desired disulfides even on a large scale by reaction of Bunte salts with imidazole in good to high yields in aqueous media.

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